Patents

US 12735628 B1: Rapid-darkening, wavelength-tunable photochromic compositions, systems, and methods

Granted
2026-09-15
Filed
2023-05-13 application 18197058
Type
Utility · 19 claims
Elsewhere
Google Patents ↗ · USPTO patent document ↗ · USPTO Patent Center record ↗

Abstract

Rapid-darkening and wavelength-tunable photochromic compositions and systems are disclosed. Nanoparticles photochromically darken in response to incident light by photo-oxidizing a dopant to reversibly create an optically absorbing mid-gap electronic state. The wavelengths that trigger photochromic darkening as well as the absorbed wavelengths may be tuned by changing the nanoparticle composition, the nanoparticle size, and/or the dopant. The time for reversal of darkening may be tuned using hole-accepting ligands attached to the nanoparticles as well as hole-accepting molecules adjacent to the nanoparticles. Some variations provide a photochromic composition comprising: semiconductor nanoparticles that do not include ZnS, ZnSe, ZnTe, or ZnInS; transition-metal dopant particles; and organic ligands bonded to the semiconductor nanoparticles, wherein the organic ligands contain a carboxylate functional group, a thiol functional group, an amine functional group, or a combination thereof. In the disclosed systems, there is an on/off switch for the photochromic function. Many photochromic uses are described.

Source: PTBLXML, file of 2026-09-15 (ipgb20260915.xml).

Assignees

AssigneeTypePlaceAlso on furp.orgSource
HRL Laboratories, LLC 1,601 patentsUS company or organizationMalibu, CAPTBLXML, file of 2026-09-15

Inventors

InventorPlacePatentsPerson pageSource
Adam GrossSanta Monica, CAPTBLXML, file of 2026-09-15
Erik CrenshawLos Angeles, CA5PTBLXML, file of 2026-09-15
Shirell KleinLos Angeles, CA4PTBLXML, file of 2026-09-15
Gregory RutkowskiCalabasas, CA4PTBLXML, file of 2026-09-15

CPC categories

SubclassCategoryFirst groupSource
C09KMaterials for miscellaneous applications, not provided for elsewhereC09K9/00PTBLXML, file of 2026-09-15
G02FOptical devices or arrangements for the control of light by modification of the optical properties of the media of the elements involved therein; non-linear optics; frequency-changing of light; optical logic elements; optical analogue/digital convertersG02F1/0121PTBLXML, file of 2026-09-15
B82YSpecific uses or applications of nanostructures; measurement or analysis of nanostructures; manufacture or treatment of nanostructuresB82Y20/00PTBLXML, file of 2026-09-15

Cooperative Patent Classification, as currently assigned (one row per subclass).

Assignments and security interests

No recorded assignments or security interests on file for this patent.

USPTO bulk data: PatentsView granted patents, disambiguated (PVGPATDIS) for patents, assignees, inventors, places and CPC categories; the USPTO Patent Assignment Dataset (ECORSEXC) for assignments and security interests. Patents filed in the last 20 years. No claims or full text. Links to other records are by name (and state): EXACT means the identical full name and state; FUZZY means a looser name match, with the confidence shown.