Patents

US 12606491 B2: Preceramic 3D-printing monomer and polymer formulations

Granted
2026-04-21
Filed
2024-02-23 application 18585284
Type
Utility · 23 claims
Elsewhere
Google Patents ↗ · USPTO patent document ↗ · USPTO Patent Center record ↗

Abstract

This disclosure provides resin formulations which may be used for 3D printing and thermally treating to produce a ceramic material. The disclosure provides direct, free-form 3D printing of a preceramic polymer, followed by converting the preceramic polymer to a 3D-printed ceramic composite with potentially complex 3D shapes. A wide variety of chemical compositions is disclosed, and several experimental examples are included to demonstrate reduction to practice. For example, preceramic resin formulations may contain a carbosilane in which there is at least one functional group selected from vinyl, allyl, ethynyl, unsubstituted or substituted alkyl, ester group, amine, hydroxyl, vinyl ether, vinyl ester, glycidyl, glycidyl ether, vinyl glycidyl ether, vinyl amide, vinyl triazine, vinyl isocyanurate, acrylate, methacrylate, alkyl acrylate, alkyl methacrylate, phenyl, halide, thiol, cyano, cyanate, or thiocyanate. The resin formulations may contain a solid-phase filler, to provide high thermal stability and mechanical strength (e.g., fracture toughness) in the final ceramic material.

Source: PTBLXML, file of 2026-04-21 (ipgb20260421.xml).

Assignees

AssigneeTypePlaceAlso on furp.orgSource
HRL Laboratories, LLC 1,601 patentsUS company or organizationMalibu, CAPTBLXML, file of 2026-04-21

Inventors

InventorPlacePatentsPerson pageSource
Zak C. EckelThousand Oaks, CA52PTBLXML, file of 2026-04-21
Andrew P. NowakLos Angeles, CA128PTBLXML, file of 2026-04-21
Ashley M. DustinSanta Monica, CA49PTBLXML, file of 2026-04-21
April R. RodriguezSanta Monica, CA47PTBLXML, file of 2026-04-21
Phuong BuiThousand Oaks, CA21PTBLXML, file of 2026-04-21
Tobias A. SchaedlerOak Park, CA81PTBLXML, file of 2026-04-21

CPC categories

SubclassCategoryFirst groupSource
C04BLime, magnesia; slag; cements; compositions thereof, e.g. mortars, concrete or like building materials; artificial stone ; ceramics ; refractories; treatment of natural stoneC04B35/571PTBLXML, file of 2026-04-21
B28BShaping clay or other ceramic compositions; shaping slag; shaping mixtures containing cementitious material, e.g. plasterB28B1/001PTBLXML, file of 2026-04-21
B33YAdditive manufacturing, i.e. manufacturing of three-dimensional [3d] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3d printing, stereolithography or selective laser sinteringB33Y70/00PTBLXML, file of 2026-04-21
C08GMacromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bondsC08G77/50PTBLXML, file of 2026-04-21

Cooperative Patent Classification, as currently assigned (one row per subclass).

Assignments and security interests

No recorded assignments or security interests on file for this patent.

USPTO bulk data: PatentsView granted patents, disambiguated (PVGPATDIS) for patents, assignees, inventors, places and CPC categories; the USPTO Patent Assignment Dataset (ECORSEXC) for assignments and security interests. Patents filed in the last 20 years. No claims or full text. Links to other records are by name (and state): EXACT means the identical full name and state; FUZZY means a looser name match, with the confidence shown.